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Surface-Modified Nanoclays for Enhancing Resistance to Moisture Damage in Hot Mix Asphalt

Received: 27 February 2024     Accepted: 25 March 2024     Published: 17 May 2024
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Abstract

Previous research indicated that nanomaterials have potential in improving pavement properties, particularly moisture resistance. This study evaluated the effectiveness of nanoclays in enhancing the resistance of Hot Mix Asphalt (HMA) to moisture damage and compared its performance to standard modifiers. Asphalt binder modified using four additives was tested using a Dynamic Shear Rheometer (DSR) before and after being aged in a Rolling Thin Film Oven (RTFO): two surface-modified nanoclays and two liquid anti-stripping chemicals (HP+ and LOF 6500). The DSR and RTFO tests showed that the two nanoclays had a stiffening effect on the binder, while both liquid antistripping agents had the opposite effect, decreasing both the elastic and complex modulus of the binder. After RTFO aging, similar trends were observed, except the binder had become much stiffer in all cases. HMA designed employing the Superpave mix design procedure was tested for moisture sensitivity in accordance with AASHTO T-283. The dry tensile strength for the two nanoclays and LOF 6500 modified mixes were higher than the control mix. However, all modified mixes resulted in wet tensile strengths that were higher than the control. The tensile strength ratios for all modified mixes were also higher than the control and exceeded the Superpave mix design method minimum of 0.80. Evaluation of these additives in the field would further benefit asphalt pavement research.

Published in American Journal of Civil Engineering (Volume 12, Issue 3)
DOI 10.11648/j.ajce.20241203.11
Page(s) 76-85
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Nanoclay, Moisture Resistance, Hot Mix Asphalt, Anti-Stripping

References
[1] Behbahani, H.; Hamedi, G. H.; Moghaddam Gilani, V. N. (2020). Effects of asphalt binder modifying with nano hydrated lime on moisture susceptibility of asphalt mixtures with thermodynamically concepts. Petroleum Science and Technology, 38(4), 297-302.
[2] Kringos, N., & Scarpas, A. (2008). Physical and mechanical moisture susceptibility of asphaltic mixtures. International Journal of Solids and Structures, 45(9), 2671-2685.
[3] Esarwi, A. M., Hainin, M. R., & Chik, A. A. (2008). Stripping resistance of malaysian hot mix asphalt mixture using hydrated lime as filler. In EASTS International Symposium on Sustainable Transportation incorporating Malaysian Universities Transport Research Forum Conference, Malaysia.
[4] Hicks, R. G. (1991). Moisture damage in asphalt concrete, NCHRP synthesis of highway practice 175. Transportation Research Board, Washington, DC.
[5] Terrel, R. L., & Al-Swailmi, S. (1994). Water sensitivity of asphalt-aggregate mixes: test selection (No. SHRP-A-403).
[6] Chakravarty, H., & Sinha, S. (2020a). Moisture damage of bituminous pavements and application of nanotechnology in its prevention. Journal of Materials in Civil Engineering, 32(8), 03120003.
[7] Kennedy, T. W., Roberts, F. L., & Lee, K. W. (1983). Evaluation of moisture effects on asphalt concrete mixtures (No. 911).
[8] Roberts, F. L., Kandhal, P. S., Brown, E. R., Lee, D. Y., & Kennedy, T. W. (1991). Hot mix asphalt materials, mixture design and construction.
[9] Tunnicliff, D. G., & Root, R. E. (1984). Use of Antistripping Additives in Asphaltic Concrete Mixtures Laboratory Phase. NCHRP Report, (Laboratory Phase).
[10] Anderson, D. A., Dukatz, E. L., & Petersen, J. C. (1982). The effect of antistrip additives on the properties of asphalt cement. In Association of Asphalt Paving Technologists Proceedings (Vol. 51).
[11] Epps, J., Berger, E., & Anagnos, J. N. (2003). Treatments in Moisture Sensitivity of Asphalt Pavements. Transportation Research Board: Washington, DC, USA.
[12] Huang, B., Shu, X., Dong, Q., & Shen, J. (2010). Laboratory evaluation of moisture susceptibility of hot-mix asphalt containing cementitious fillers. Journal of Materials in Civil Engineering, 22(7), 667-673.
[13] Ameli, A., Babagoli, R., Khabooshani, M., AliAsgari, R., & Jalali, F. (2020). Permanent deformation performance of binders and stone mastic asphalt mixtures modified by SBS/montmorillonite nanocomposite. Construction and Building Materials, 239, 117700.
[14] Arabani, M., Haghi, A., & Tanzadeh, R. (2015). Effects of nanoclay on mechanical properties of aged asphalt mixture. Chem Technol Key Dev Appl Chem Biochem Mater Sci, 49, 766-773.
[15] Ashish, P. K., Singh, D., & Bohm, S. (2016). Evaluation of rutting, fatigue and moisture damage performance of nanoclay modified asphalt binder. Construction and Building Materials, 113, 341-350.
[16] Oldham, D., Mallick, R., & Fini, E. H. (2021). Reducing susceptibility to moisture damage in asphalt pavements using polyethylene terephthalate and sodium montmorillonite clay. Construction and Building Materials, 269, 121302.
[17] Iskender, E. (2016). Evaluation of mechanical properties of nano-clay modified asphalt mixtures. Measurement, 93, 359-371.
[18] Ezzat, H., El-Badawy, S., Gabr, A., Zaki, S., & Breakah, T. (2020). Predicted performance of hot mix asphalt modified with nano-montmorillonite and nano-silicon dioxide based on Egyptian conditions. International Journal of Pavement Engineering, 21(5), 642-652.
[19] Gedafa, D. S., Karki, B., Berg, A., Saha, R., & Melaku, R. S. (2019). Effect of nanomaterials on cracking and rutting resistance of HMA. In Airfield and highway pavements 2019: Innovation and sustainability in highway and airfield pavement technology (pp. 88-95). Reston, VA: American Society of Civil Engineers.
[20] de Melo, J. V. S., Trichês, G., & de Rosso, L. T. (2018). Experimental evaluation of the influence of reinforcement with Multi-Walled Carbon Nanotubes (MWCNTs) on the properties and fatigue life of hot mix asphalt. Construction and Building Materials, 162, 369-382.
[21] López-Montero, T., Crucho, J., Picado-Santos, L., & Miró, R. (2018). Effect of nanomaterials on ageing and moisture damage using the indirect tensile strength test. Construction and Building Materials, 168, 31-40.
[22] Fakhri, M., & Mottahed, A. R. (2021). Improving moisture and fracture resistance of warm mix asphalt containing RAP and nanoclay additive. Construction and Building Materials, 272, 121900.
[23] Mansourian, A., Goahri, A. R., & Khosrowshahi, F. K. (2019). Performance evaluation of asphalt binder modified with EVA/HDPE/nanoclay based on linear and non-linear viscoelastic behaviors. Construction and Building Materials, 208, 554-563.
[24] You, Z., Mills-Beale, J., Foley, J. M., Roy, S., Odegard, G. M., Dai, Q., & Goh, S. W. (2011). Nanoclay-modified asphalt materials: Preparation and characterization. Construction and Building Materials, 25(2), 1072-1078.
[25] Hossain, Z., Zaman, M., Saha, M. C., & Hawa, T. (2015). Evaluation of Moisture Susceptibility and Healing Properties of Nanoclay-Modified Asphalt Binders. In IFCEE 2015 (pp. 339- 348).
[26] Ameri, M., Nobakht, S., Bemana, K., Vamegh, M., & Rooholamini, H. (2016). Effects of nanoclay on hot mix asphalt performance. Petroleum Science and Technology, 34(8), 747- 753.
[27] Yang, Z., Zhang, Y., & Shi, X. (2018). Impact of nanoclay and carbon microfiber in combating the deterioration of asphalt concrete by non-chloride deicers. Construction and Building Materials, 160, 514-525.
Cite This Article
  • APA Style

    Rahim, A., Badawy, A. E., Cox, T. (2024). Surface-Modified Nanoclays for Enhancing Resistance to Moisture Damage in Hot Mix Asphalt. American Journal of Civil Engineering, 12(3), 76-85. https://doi.org/10.11648/j.ajce.20241203.11

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    ACS Style

    Rahim, A.; Badawy, A. E.; Cox, T. Surface-Modified Nanoclays for Enhancing Resistance to Moisture Damage in Hot Mix Asphalt. Am. J. Civ. Eng. 2024, 12(3), 76-85. doi: 10.11648/j.ajce.20241203.11

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    AMA Style

    Rahim A, Badawy AE, Cox T. Surface-Modified Nanoclays for Enhancing Resistance to Moisture Damage in Hot Mix Asphalt. Am J Civ Eng. 2024;12(3):76-85. doi: 10.11648/j.ajce.20241203.11

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  • @article{10.11648/j.ajce.20241203.11,
      author = {Ashraf Rahim and Amro El Badawy and Travis Cox},
      title = {Surface-Modified Nanoclays for Enhancing Resistance to Moisture Damage in Hot Mix Asphalt
    },
      journal = {American Journal of Civil Engineering},
      volume = {12},
      number = {3},
      pages = {76-85},
      doi = {10.11648/j.ajce.20241203.11},
      url = {https://doi.org/10.11648/j.ajce.20241203.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajce.20241203.11},
      abstract = {Previous research indicated that nanomaterials have potential in improving pavement properties, particularly moisture resistance. This study evaluated the effectiveness of nanoclays in enhancing the resistance of Hot Mix Asphalt (HMA) to moisture damage and compared its performance to standard modifiers. Asphalt binder modified using four additives was tested using a Dynamic Shear Rheometer (DSR) before and after being aged in a Rolling Thin Film Oven (RTFO): two surface-modified nanoclays and two liquid anti-stripping chemicals (HP+ and LOF 6500). The DSR and RTFO tests showed that the two nanoclays had a stiffening effect on the binder, while both liquid antistripping agents had the opposite effect, decreasing both the elastic and complex modulus of the binder. After RTFO aging, similar trends were observed, except the binder had become much stiffer in all cases. HMA designed employing the Superpave mix design procedure was tested for moisture sensitivity in accordance with AASHTO T-283. The dry tensile strength for the two nanoclays and LOF 6500 modified mixes were higher than the control mix. However, all modified mixes resulted in wet tensile strengths that were higher than the control. The tensile strength ratios for all modified mixes were also higher than the control and exceeded the Superpave mix design method minimum of 0.80. Evaluation of these additives in the field would further benefit asphalt pavement research.
    },
     year = {2024}
    }
    

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  • TY  - JOUR
    T1  - Surface-Modified Nanoclays for Enhancing Resistance to Moisture Damage in Hot Mix Asphalt
    
    AU  - Ashraf Rahim
    AU  - Amro El Badawy
    AU  - Travis Cox
    Y1  - 2024/05/17
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    N1  - https://doi.org/10.11648/j.ajce.20241203.11
    DO  - 10.11648/j.ajce.20241203.11
    T2  - American Journal of Civil Engineering
    JF  - American Journal of Civil Engineering
    JO  - American Journal of Civil Engineering
    SP  - 76
    EP  - 85
    PB  - Science Publishing Group
    SN  - 2330-8737
    UR  - https://doi.org/10.11648/j.ajce.20241203.11
    AB  - Previous research indicated that nanomaterials have potential in improving pavement properties, particularly moisture resistance. This study evaluated the effectiveness of nanoclays in enhancing the resistance of Hot Mix Asphalt (HMA) to moisture damage and compared its performance to standard modifiers. Asphalt binder modified using four additives was tested using a Dynamic Shear Rheometer (DSR) before and after being aged in a Rolling Thin Film Oven (RTFO): two surface-modified nanoclays and two liquid anti-stripping chemicals (HP+ and LOF 6500). The DSR and RTFO tests showed that the two nanoclays had a stiffening effect on the binder, while both liquid antistripping agents had the opposite effect, decreasing both the elastic and complex modulus of the binder. After RTFO aging, similar trends were observed, except the binder had become much stiffer in all cases. HMA designed employing the Superpave mix design procedure was tested for moisture sensitivity in accordance with AASHTO T-283. The dry tensile strength for the two nanoclays and LOF 6500 modified mixes were higher than the control mix. However, all modified mixes resulted in wet tensile strengths that were higher than the control. The tensile strength ratios for all modified mixes were also higher than the control and exceeded the Superpave mix design method minimum of 0.80. Evaluation of these additives in the field would further benefit asphalt pavement research.
    
    VL  - 12
    IS  - 3
    ER  - 

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